Lead in plastics – Recycling of legacy material and appropriateness of current regulations

Abstract

X-ray fluorescence spectrometry has been employed to measure Pb in a wide range of consumer and environmental plastics, including food-packaging material, household goods, electronic casings, beach litter and agricultural waste. Results reveal high concentrations of Pb (>1000 mg kg-1) in historical items that are still in use or circulation (e.g. toys, construction plastics, wiring insulation) and variable, but generally lower concentrations in more recently manufactured articles. Analysis of Br, Cl and Cr, proxies for brominated flame retardants, polyvinyl chloride (PVC) and chromate pigments, respectively, suggests that as historical material is recycled, Pb from electronic plastics and pigments, but not PVC, is dispersed into a variety of newer products. Although most cases in the consumer sector comply with relevant EU Directives, some products that are non-compliant highlight shortfalls in regulations where recycling is involved and potential problems arising from the direct fashioning of industrial plastics into new consumer goods through attempts to be environmentally positive. The uncontrolled loss of historical and recycled plastics has also resulted in Pb contamination of the environment. Here, it is proposed that litter can be classified as hazardous depending on its Pb content and according to existing regulations that embrace consumer plastics.