Abstract
Continuous-flow cold vapour- atomic fluorescence spectrometry is shown to be an extremely sensitive technique for the determination of mercury with detection limits typically below 0.01 mug l(-1). Linear calibration ranges were found to be at least four orders of magnitude (i.e. up to 0.1 mg l(-1)). Samples with concentrations exceeding the linear range are susceptible to self-absorption, and may, in severe cases, cause carry-over problems between samples. The flow-injection approach has been utilized to extend the upper limit of the linear calibration range allowing determinations up to 10 mg l(-1) of mercury. A range of certified reference materials and zinc battery anodes have been successfully analysed with a minimal number of sample dilutions.
DOI
10.1155/S1463924691000421
Publication Date
1991-01-01
Publication Title
J Automat Chem
Volume
13
Issue
6
First Page
267
Last Page
271
ISSN
0142-0453
Organisational Unit
School of Geography, Earth and Environmental Sciences
Recommended Citation
Corns, W. T., Ebdon, L., Hill, S., & Stockwell, P. (1991) 'Automated cold vapour flow-injection analysis of mercury at high concentrations.', J Automat Chem, 13(6), pp. 267-271. Available at: https://doi.org/10.1155/S1463924691000421
