Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation.

Authors

Christopher M.A. Parlett, Rutherford Appleton Laboratory
Aleksandra Ziarko, Aston University
Thomas J.A. Slater, Cardiff University
Mark A. Isaacs, RAL
Lee J. Durndell, School of Geography, Earth and Environmental Sciences

ORCID

• Lee J. Durndell: 0000-0002-2391-5233

Abstract

Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.

DOI

10.1039/d3cy00198a

Publication Date

2023-05-12

Publication Title

Catalysis Science & Technology

ISSN

2044-4753

Embargo Period

2023-05-16

Recommended Citation

Parlett, C., Ziarko, A., Slater, T., Isaacs, M., & Durndell, L. (2023) 'Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation.', Catalysis Science & Technology, . Available at: 10.1039/d3cy00198a