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dc.contributor.supervisorDijkstra, Arjan
dc.contributor.authorMarien, Christian
dc.contributor.otherSchool of Geography, Earth and Environmental Sciencesen_US
dc.date.accessioned2019-08-14T16:34:03Z
dc.date.available2019-08-14T16:34:03Z
dc.date.issued2019
dc.identifier10511184en_US
dc.identifier.urihttp://hdl.handle.net/10026.1/14799
dc.descriptionMarien, C., Dijkstra, A.H. and Wilkins, C., 2018. The hydrothermal alteration of carbonatite in the Fen Complex, Norway: mineralogy, geochemistry, and implications for rare-earth element resource formation. Mineralogical Magazine, 82(S1): S115-S131.en_US
dc.description.abstract

The Fen Complex in Norway consists of a composite carbonatite-ijolite-pyroxenite diatreme intrusion. Locally, the hydrothermally altered, hematite-rich rock rødbergite exhibited high grades (up to 2.1 wt% REE) of rare earth elements (REE). In order to secure the supply of REE for future technology markets in Europe, it becomes increasingly important to establish potential domestic REE sources like the Fen Complex. This project aims to develop a model for the carbonatite-hosted hydrothermal REE deposit (‘Rødbergite’) in the Fen Complex, Norway. SEM and ICP-MS trace element analyses of 73 bulk samples taken along various geological key transects showed the transformation of carbonatite, damtjernite, gneiss and fenite to rødbergite. An alteration mineral assemblage of dolomite, Fe-dolomite, barite, Ba-bearing phlogopite, hematite with accessory apatite, calcite, monazite-(Ce) and quartz replaced the original minerals of the protolith. The transformation to rødbergite is accompanied by an increase in REE concentrations (up to 23-fold) — mainly light REE— and Th. The overall REE concentration of rødbergite varies strongly and depends on the REE concentration of the protolith, density of hydrothermal micro-veins — containing monazite, bastnäsite, synchysite and allanite — and locally apatite relics. While Th-Pb geochronology of zircons established a robust age for the emplacement of the Fen Complex carbonatite with 550 Ma ± 10 Ma, monazite from rødbergite gave U-Pb and Th-Pb ages of 272 Ma ± 5 Ma and 272 Ma ± 10 Ma respectively. The age of the REE-mineralisation coincides with the Oslo rift formation, which is interpreted as the heat source triggering the hydrothermal formation of rødbergite at the Fen Complex The major findings are combined in a new ore deposit model for rødbergite that can help to improve exploration strategies in the Fen complex and has implications for carbonatite-hosted hydrothermal REE resources around the world.

en_US
dc.description.sponsorshipNERC Isotope Geosciences Facilities Steering Committeeen_US
dc.language.isoen
dc.publisherUniversity of Plymouth
dc.subjectCarbonatiteen_US
dc.subjectHydrothermal Alterationen_US
dc.subjectRare Earth Elementsen_US
dc.subjectREEen_US
dc.subjectFen Complexen_US
dc.subjectMineralisationen_US
dc.subjectRødbergiteen_US
dc.subject.classificationPhDen_US
dc.titleTHE HYDROTHERMAL RARE EARTH ELEMENT MINERALISATION AT THE PERALKALINE CARBONATITE FEN COMPLEX IN NORWAYen_US
dc.typeThesis
plymouth.versionpublishableen_US
dc.identifier.doihttp://dx.doi.org/10.24382/604
dc.rights.embargoperiodNo embargoen_US
dc.type.qualificationDoctorateen_US
rioxxterms.versionNA
plymouth.orcid_idhttps://orcid.org/0000-0002-3217-3956en_US


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